Monday AM

Room MDCL1305-07

Plenary

Chair(s) - Michael Brook, William Leigh

08:00 Introductory Remarks
08:15 00001 The Structure and Reactivity of the Silicon-Oxygen Bond: Present and Future Perspectives ^*$Bassindale A.R., Taylor P.G.
09:10 End of Session

Room MDCL1110

Bioinspired Organosilicon Chemistry

Chair(s) - Peter Taylor

09:15 00002 The Carbon-Silicon Switch Strategy as a Tool for Odorant Design Tacke R.
09:45 Coffee Break
10:00 00003 Disila-Analogues of the Retinoids EC23 and TTNN ^$Gluyas J.B.G., Burschka C., ^*Tacke R.
10:20 00004 pH-Responsive Bridged Silsesquioxanes as Potential New Efficient Carriers for Delivery Systems Carcel C., Theron C., Fertier L., Trens P, Wong Chi Man M.
10:40 00005 Synthesis and Biological Evaluation of Silicon-Containing Dipeptidic Sweeteners Dörrich S., Falgner S., Schweeberg S., Burschka C., Brodin P., ^*$Tacke R., Wissing B.-M., Bauer U., Schell P.
11:00 00006 Synthesis and Dynamic Stereochemistry of the Novel Hypercoordinate Silicon Derivatives of 2-Amino Acids ^*$Negrebetsky V.V., Nikolin A.A., Fang H.C., Bowden A., Taylor P.G., Bassindale A.R., Baukov Y.I.
11:20 00007 Shortening the Discovery Path. Streamlined Silane Protease Inhibitor Synthesis, Supporting Chemistry Studies and New Structures ^*$Sieburth S.M., Bo Y., Singh S., Duong H.Q., Cao C.
11:50 End of Session

Room MDCL1309

Functional Silica Surfaces

Chair(s) - Richard Laine

09:15 00008 Functional Materials from Crosslinked Hybrid Sol-Gels: Chemical Diversity for Corrosion Prevention Coatings ^*$Vreugdenhil A.J., Stotesbury T.E.
09:45 Coffee Break
10:00 00009 Dehydrocarbon Polycondensation of PhSiH3 with (MeO)4Si Catalyzed by Tris(pentafluorophenyl)borane as a New Route to Silicone Resins. ^*$Kurjata J., Fortuniak W., Rubinsztajn S., Chojnowski J.
10:20 00010 New Insights on Novel Water-Borne Sol-Gel Systems for Corrosion Protection Formulations Albert P., ^*Sanchez-Morillo R.
10:40 00011 Synthesis and Study of Epoxy-Silica Ceramer as Binder for Protective Coatings ^*$Bakhshandeh E., Jannesari A., Ranjbar Z.
11:00 00012 Inductive Heating by Silica-Coated Iron Oxides Herzog H.
11:20 00013 Structure vs Properties in Silicone Rubbers. Part 2: Influence of Fumed Silica Modification in High Consistency Rubbers (HCR) ^*Mariot D., Pouget E., Saint-Jalmes L., Vovelle L., Ganachaud F.
11:40 End of Session

Room MDCL1105

Functional Silicones

Chair(s) - Emmanuel Pouget

This session is supported by Siltech Corporation

09:15 00014 Living Polymerization Routes to Dual Functional Silicones Arkles B., Goff J., Olenick L., Kimble E., Larson G., Cameron R.
09:45 Coffee Break
10:00 00015 Aminosilanes as Useful Intermediates and Carbon Dioxide as an Oxygen Source for Polysiloxanes ^*$Kroke E., Wiltzsch C., Kraushaar K., Schwarzer A., Roewer G., Wagler J.
10:20 00016 Boronic Acid-Functionalized Silicones Dodge L., Chen Y., Gonzaga F., ^$Brook M.A.
10:40 00017 Structure vs Properties in Silicone Rubbers. Part 1: Influence of Silicone Architectures in Liquid Silicone Rubbers (LSR) Delebecq E., Flers A., ^*Ganachaud F.
11:00 00018 Silicone- Modified Epoxy Resin: Effect of Molecular Weight and Content of PDMS on Morphology ^$Sobhani S., ^*Jannesari A., Bastani S.
11:20 00019 Straightforward Preparation of Copolymers Based on Polydimethylsiloxane and Alkylamine Leymarie L., Chaumont P., Pouget E., Dupuy J., Sintes-Zydowicz N., ^$Fleury E.
11:50 End of Session

Room MDCL1305-07

Silylenes

Chair(s) - Tsuyoshi Kato

09:15 00020 Ylide-Like Silylenes in Concert: Lessons from Silicon-Based Small Molecule Activation ^*$Driess M., Yao S., Xiong Y., Praesang C., Stoelzel M., Asay M.
09:45 Coffee Break
10:00 00021 Resonance and Stability in Heterocyclic Metallylenes. A Theoretical Prediction of a New Stable Silylene Karni M., Apeloig Y.
10:20 00022 Stable Phosphine-Stabilized Silicon(II)-Hydride Rodriguez R., Kato T.K., Saffon-Merceron N., ^$Baceiredo A.B., Cossío F.P.
10:40 00023 A Gas-Phase Kinetic and Theoretical Study of the Reaction of ClSiH with Trimethylsilane-1-d: Should kD be Less or Greater than kH? ^*$Becerra R., Walsh R., Boganov S.E., Krylova I.V., Promyslov V.M.
11:00 00024 Steric and Electronic Effects on the Kinetics and Thermodynamics of Complexation of Transient Silylenes and Germylenes with O-, S-, N- and P-Donors Kostina S.S., Singh T., ^*$Leigh W.J.
11:20 00025 Molecular Tailoring: Internal Catalytic Effect of Bulky Substituents ^*$Veszprémi T., Szilvási T.
11:50 End of Session

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Bold text denotes the presenting author.   If present, ^* denotes the corresponding author and ^$ denotes the principal investigator.

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