Monday PM

Room MDCL1305-07

Flash Presentations

Chair(s) - Joyce Corey

13:25 Flash Presentations selected from the Monday poster session

13:55 End of Session

Room MDCL1102

Complex Structures

Chair(s) - Claire Tessier

14:00 00026 Zwitterionic Alkaline and Alkaline Earth Metal Silanides: Synthesis, Structure and Reactivity ^*$Krempner C.
14:30 00027 Syntheses and Reactivity of Stable Silicon Clusters with Partial Substitution ^$Abersfelder K., White A.J.P., Rzepa H.S., ^*Scheschkewitz D.
14:50 00028 Racemization versus Retention of Chiral Information during the Formation of Silicon and Tin Complexes Böhme U., Warncke G., Fels S., Günther B., Kronstein M.
15:10 00029 Chemical Transformations involving Perhydropentasilanes Stueger H., Walkner C., Mitterfellner T.
15:30 Coffee Break
15:50 00030 Mono- and Bicyclic Disilylated Germylenes and Related Compounds ^*Hlina J.A., Baumgartner J., ^$Marschner C.
16:10 00031 Chemistry in the Periphery of the Si=Si Bond Jeck J., Abersfelder K., Meltzer A., Cowley M., ^*$Scheschkewitz D.
16:30 00032 New Perspectives for "Non-Classical" Molecules: Heavy [1.1.1]Propellanes of Group 14 ^*Breher F., Nied D., Klopper W., Augenstein T.
17:00 End of Session

Room MDCL1309

Silica and Silsesquioxanes

Chair(s) - Andrew Vreugdenhil

14:00 00033 Synthesis and Application of Small Siloxane Molecules Obtained from Natural Silicates ^*$Cervantes J., Lira-Negrete O., Villegas A., Alvarez G., Morales J., Caudillo M.
14:30 00034 Functionalization of POSS Compounds via Various Catalytic Methods and their Applications in Polymer Nanocomposites Dutkiewicz M., ^*$Marciniec B., Maciejewski H., Sadej M., Andrzejewska E., Zielecka M.
14:50 00035 Novel Sol-Gel Precursors for Thin Mesoporous Eu3+-Doped Silica Coatings as Efficient Luminescence Materials Feinle A., ^*Hüsing N., Lavoie-Cardinal F., Wickleder C.
15:10 00036 Effect of Hydrothermal Treatment on Adsorption Properties of Silica Gel Studied by Near Infrared Spectroscopy ^*$Christy A. A.
15:30 Coffee Break
15:50 00037 Effect of Silica Nanoparticles in Organic Semiconductors for Organic-TFT containing Polysilesquioxane Gate Insulator ^*$Matsukawa K., Yamazaki S., Tokai S., Nagase T., Watase S., Watanabe M., Naito H.
16:10 00038 Facile Synthesis of Novel Functionalized Silsesquioxane Nanostructures containing an Encapsulated Fluoride Anion ^*$El Aziz Y., Bassindale A.R., Taylor P.G.
16:30 00039 Polysilsesquioxanes with New Structures and Function ^*$Kawakami Y.
17:00 End of Session

Room MDCL1110

Siloxanes at Biointerfaces

Chair(s) - Paul Zelisko

14:00 00040 Silicone Biomaterial Applications: Past, Present and Future ^*Curtis J.M.
14:30 00041 Silicones and Modified Silicones at Biological Interfaces ^*$Sheardown H.D., Liu L., Klenkler B., Brook M.A.
14:50 00042 Market Trends for Silicones in Medical and Pharmaceutical Applications Stephenson J.
15:10 00043 Surface Functionalization of Silica Nanoparticles with Cysteine: A Low-Fouling Zwitterionic Surface Rosen J., ^*$Gu F.
15:30 Coffee Break
15:50 00044 Preparation and Polymerization of Silicone Microemulsions Whinton M., Li N., Chen Y., ^$Brook M.A.
16:10 00045 Polysiloxane Soft Gels as Injectable, in situ Curable Accommodating IOLs ^*Hao X., Hughes T.C., Donovan L., Fernandez V, Ho A., Jeffery J.L., Manns F., Parel J.M., Wilkie J.S., Denham D.
16:30 00046 In situ Curable Siloxane Gels, Restoring the Eye's Ability to Near Focus ^*Hughes T.C., Hao X., Le T.P.T., Balachandra A., Huang F., Johnston G., McFarland G., Ho A., Manns F., Parel J.M., Navkivil D., Mohamed A., Taneja M., Veerendranath P.
17:00 End of Session

Room MDCL1105

Synthetic Applications of Silicon Chemistry

Chair(s) - Norbert Auner

14:00 00047 New Methods for Stereoselective Synthesis Based on the Reactions of Silylenes ^*$Woerpel K.A.
14:30 00048 Synthesis and Application of 2-Silyl-Substituted Pyrrolidines in Asymmetric Organocatalysis Bauer J.O., ^*Strohmann C.
14:50 00049 Tris(trimethylsilyl)silyl-N,N-dimethylmethaneamide: A Highly Efficient and Convenient Reagent for Acid Catalyzed Hypersilyl Protection of Alcohols and Thiols Alvi M.R., Tibbelin J., Jahn B., ^*Ottosson H.
15:10 00050 Activation of Nitriles by Trichloro(2-dialkylphosphinoimidazol-1-yl)silanes: Synthesis and Characterization of Novel Dinuclear Pentacoordinate Silicon(IV) Complexes Junold K., Burschka C., ^*$Tacke R.
15:30 Coffee Break
15:50 00051 Fluorocarbofunctional Organosilicon Compounds as Precursors of Highly Hydrophobic Materials ^*$Maciejewski H., Karasiewicz J., Dutkiewicz M., Marciniec B.
16:10 00052 Practical Synthesis of Alkoxysilanes via Selective Cleavage of the C-O Bond in Unsymmetrical Ethers Wakabayashi R., Sugiura Y., ^*Kuroda K.
16:30 00053 Silenes for Organic Synthesis ^*$Steel P.G.
17:00 End of Session

MUSC Marketplace

Posters

Chair(s) - Michael Brook

From 17:00 until 19:00

17:00 00054 Structure Investigation of Porous Silica-Titania Monoliths and Europium(III) Doped-Silica Coated Thin Films via SAXS Akbarzadeh J., Flaig S., Feinle A., Huesing N., Peterlik H.
17:00 00055 The Synthesis of Doped Si Nanoparticles for Biological Imaging through Microwave Chemistry Atkins T.M., Singh M.P., ^*Louie A.Y., ^$Kauzlarich S.M.
17:00 00056 Reactivity Studies of Germanium(II) and Tin(II) Cations Avery J.C., ^*$Baines K.M.
17:00 00057 Using Mesoporous Encapsulated Silicon Nanocrystals for Drug Delivery Applications Barnes M.A., ^*Regli S., ^$Veinot J.C.G.
17:00 00058 Synthesis of Disilylated Group 4 Metallocenes in the Oxidation States + 3 and +4 Arp H., Rasmussen K., Saraj N., Zark P., Müller T., Marschner C., ^*$Baumgartner J.
17:00 00059 Synthesis and Structural Studies of Silicon and Tin Complexes with O,N,O´ Schiff Base Ligands ^*Fels S., Böhme U., Brendler E.
17:00 00060 Permanently Water Wettable Silicone Elastomers Wang Y., Gonzaga F., Chen Y., Grand A.S., ^*$Brook M.A.
17:00 00061 Striking Reactivity of an Isolable Dialkylsilylene towards Substituted Imines Chen W.F., ^$Lin A.Q., Lu H., ^*Li Z.F., Kira M.
17:00 00062 Influence of (HSiO1.5)n(RSiO1.5)m Sol-Gel Polymer Structure and Composition on the Size and Luminescent Properties of Silicon-Based Nanostructures Dasog M., ^*Veinot J.G.C.
17:00 00063 Synthesis and Characterization of Mesoporous Silica SBA-16 Obtained Using a Ternary System of Copolymer- F127/Ethanol/TEOS De Oliveira V.V., ^$Airoldi C.
17:00 00064 Thermally Conductive Silicon Rubber Deng Y., Jiang J.-X., ^*Lai G.-Q.
17:00 00065 Modification of Starch/Catechu Bio-Blend Film by Silane Monomer and UV Radiation ^*Dey K., ^$Chowdhury S., Khan R.
17:00 00066 Direct Detection and Studies of the Reactivity of Diphenylstannylene in Solution by Laser Flash Photolysis Methods Duffy I.R., ^$Leigh W.J.
17:00 00067 Synthesis and Application of Novel Cyclic Carbosiloxanes Erhardt S.A., Rieger B.
17:00 00068 Application of Single-Source Precursors in the Synthesis of Porous Monolithic Silica-Titania Mixed Oxides Flaig S., ^*Hüsing N., Akbarzadeh J., Peterlik H.
17:00 00069 Synthesis of Mono- and Difunctionalized Silsesquioxanes ^$Franczyk A., Szudkowska J., ^*Marciniec B.
17:00 00070 High Stability Seven-Member Fused-Ring Organic Semiconductors containing Silicon-Bridge Bonds for Field-Effect Transistors ^*Gao J.
17:00 00071 Citrate-Silicone Reactive Surfactants and their Application to the Structured Synthesis of Noble Metal Nano-Architectures Gonzaga F., ^*Brook M.A.
17:00 00072 The Piers-Rubinsztajn Reaction: A New Strategy for the Synthesis of Functional Silicones Grande J.B, ^$Brook M.A
17:00 00073 Polymethylphenylsilane as a Photoinitiator in the Polymerisation of Vinyl Acetate: Photodegradable PVAc ^*$Holder S.J., Roberts D.R.T.
17:00 00074 The ATRP-Induced Cyclopolymerization of Bismethacrylate Tethered by Substituted Silylene Moiety Hu Z., Xu Y.-P., ^*Lai G.-Q., Luh T.-Y.
17:00 00075 Synthesis of Blue Fluorescent 1,1-Bis(diquinolinatoalumino)siloles and their Aggregation-Induced Emission Behavior Jang S., Toulokhonova I., ^*West R.
17:00 00076 Preparation and Molecular Weight Determination of Poly(diethylsiloxane-co-methylvinylsiloxane) Jin K.K., ^*Feng S.Y.
17:00 00077 Low-Coordination Intermediates in Reactions of Trifunctional Silanes with R3SiLi Kaushansky A., ^$Apeloig Y.
17:00 00078 Siladerivatives of Bicyclohexyl: Preparation, Quantum Chemical Calculations and Raman Spectroscopy Kern T., Flock M., Fischer R., ^$Hassler K.
17:00 00079 Asymmetric Synthesis of a Silanediol and its Inhibition of the Serine Protease Chymotrypsin Khatri B.B., ^*$Sieburth S.M.
17:00 00080 Synthesis and Structural Characterization of Neutral Pentacoordinate Silicon(IV) Complexes with a Tridentate Dianionic N,N,S Ligand Kobelt C., Burschka C., ^*$Tacke R.
17:00 00081 Model and Silicone Hydrogel Contact Lens Materials: The impact of the Extended Release of Hyaluronic Acid and their Use as Drug Delivery Systems ^*Guidi G., Korogiannaki M., Weeks A.K., Hsia L.M.W., ^$Sheardown H.D.
17:00 00082 Steric Effects on the Kinetics and Mechanisms of the Reactions of Transient Silylenes with Oxiranes and Thiiranes Kostina S.S., ^*$Leigh W.J.
17:00 00083 Preparation of Fluorescent Siloxane Nanoobjects by Electrospraying Technique Larkowska M., ^*Kucharski S., Barille R.
17:00 00084 Effect of Intercalant Types on the Properties of Melt Blended Metallocene Polyethylene/Metallocene Polyethylene-g-silane/Clay Nanocomposites ^*Lai S.-M., Chen W.-C., Tang S-X., Kao H.C.
17:00 00085 Polydimethylsiloxane Composites with Low Viscosity and Low Linear Volume Shrinkage Lina D., ^*Zhijie Z., Yongxia T., Zemin X.
17:00 00086 Efficient Energy Transfer from Polysilane to BODIPY Organic Dyes Lu H., Wang Q., Chen W., ^$Li Z., ^*Lai G.
17:00 00087 New Protecting Group Strategy in Disilene Chemistry Meltzer A., ^$Scheschkewitz D.
17:00 00088 Synthesis, Structure and Properties of a Stable 1,2-Bis(ferrocenyl)digermene Miyamoto H., Sasamori T., Tokitoh N.
17:00 00089 Steric and Electronic Effects on the Reactivity of Diarylsilylenes in Solution by Laser Flash Photolysis Methods Morim D.R., Bhattacharya A., ^$Leigh W.J.
17:00 00090 Synthesis and Properties of Starlike Organosilicon Compounds with a Triazine Core ^*$Naka A., Fukuda R., Ohshita J., Ishikawa M.
17:00 00091 Poly(methylvinylsiloxanes) Cross-Linked with Cage Oligosiloxane: Preparation and Physico-Chemical Properties Nyczyk A., Wojcik M., Paluszkiewicz C., Hasik M.
17:00 00092 Mechanisms of Insertion Reactions of Silylenes Nyiri K., Szilvási T., ^*Veszprémi T.
17:00 00093 Investigations of Neutral Hyperconjugative s/p-Interactions in Substituted Bis(phenylethynyl)silanes, -germanes and -methanes Emanuelsson R., Wallner A., Prasongkit J., Smith J.R., Grigoriev A., Ahuja R., ^*Ottosson H.
17:00 00094 X-Ray Structures of Silicon Compounds Derived from trans-Cinnamic Acid Palomo-Molina J., Zakai U., Peña-Hueso A., West R., ^*$Ramos-Organillo A.
17:00 00095 The Reaction of Germylene (GeH2) with 2,3-Dimethyl-1,3-butadiene in Hydrocarbon Solvents Pantaleo A.N., ^$Leigh W.J.
17:00 00096 Derivatization of Silicone Polymers via 1,3-Dipolar Cycloadditions of Activated Alkynes Pascoal M., ^*Gonzaga F., ^$Brook M.A.
17:00 00097 Reactivity of Polar Group 14 Metallenes towards Terminal Alkynes Pavelka L.C., ^*$Baines K.M.
17:00 00098 Structural Modification of Ibuprofen: An Alternative to Make New Non-Steroidal Anti-Inflammatory Drugs Pérez-Gómez D., Zakai U., West R., ^*$Ramos-Organillo A.
17:00 00099 Synthesis of Silicon and Germanium Nanoparticle Clusters Through Inter Particle Linking Purkait T.K., Xu Z., Grayson S.M., Jayawickramarajah J., ^$Fink M.
17:00 00100 Controlling the Morphology of Silica Particles formed in Non-aqueous Silicone (Pre)elastomer Dispersions Rajendra V., Gonzaga F., ^*$Brook M.A.
17:00 00101 Silyl Cationic Frustrated Lewis Pairs: A Progress Report Reißmann M., Intemann J., Panisch R., Reinhold C.R.W., ^$Müller T.
17:00 00102 Silylation for the Preparation of New Anticancer Furylamines ^*$Romanovs V., Spura J., Muravenko V., Sleiksha I., Shestakova I., Ignatovich L.
17:00 00103 Comparison of SiMe2,SiPh2 and GePh2 in Reaction with Different Alkenes Saeidi Hayeniaz Y., ^*Leigh W.J., Chitnis S., Reid M.
17:00 00104 A New Synthetic Route to Triaryl Substituted Silylium Ions Schäfer A., Schäfer A., ^*Müller T.
17:00 00105 Syntheses and Reactivities of Silanone Precursors Shin D.H., Lee S.J., Cho H.M., ^*Lee M.E, West R.
17:00 00106 Modification of Silica Gel Surface with Epichlorohydrin in the Absence of Solvent: Application for Sorption of Copper (II) ^*Silva I.M.P, ^$Claudio A.
17:00 00107 Stopped-Flow Kinetic Studies of the Reactivities of Multiply Bonded Germanium and Silicon Compounds Smith L.J., Duffy I.R., ^*$Leigh W.J., Sekiguchi A., Takeuchi K.
17:00 00108 Catalyst-free Hydrosilylation with a Si(II)-Hydride ^*Stoelzel M., Praesang C., Enthaler S., ^$Driess M.
17:00 00109 On the Mechanism of the Reaction of White Phosphorus with Silylenes Szilvási T., ^*$Veszprémi T.
17:00 00110 Electronic Structure of Bis(silyl)carbon-, Bis(silyl)silicon- and Bis(silyl)germanium-Centered Radicals (R3Si)2XE. (E = C, Si, Ge; X = H, OH, Re(CO)5, F): EPR and DFT Studies Tumanskii B., Sheberla D., Bravo-Zhivotovskii D., Molev G., Molev V., Lee V.Ya., Takanashi K., Sekiguchi A., ^$Apeloig Y.
17:00 00111 The Application of Synthetic and Natural Aluminosilicates as Initiators in Ring Opening Polymerization of Cyclosiloxanes Vallejo M. J., ^$Villegas A., Jacobo A., Martínez J.M., Ramirez E., ^*Cervantes J.
17:00 00112 An Isolable Bis-Silylene Oxide and its Metal Coordination Wang W., Inoue S., Yao S., ^*Driess M.
17:00 00113 Towards Soluble Metallasilatrane Complexes ^*Warncke G., ^$Wagler J.
17:00 00114 Studies on the Preparation and Properties of Fluorosilicone Elastomers Wu J.
17:00 00115 Synthesis of a New Cyclic Silylene Xiao X.-Q., He X.-L., Xu Z., ^*Li Z.-F., Kira M., Jiang J.-X., ^$Lai G.-Q.
17:00 00116 Facile, Efficient and Modular Synthesis of Functional Polysiloxanes via Thiol-Ene Click Chemistry Xue L., ^*Feng S.Y. WITHDRAWN
17:00 00117 Neighboring Acetal-Assisted Brønsted Acid Catalyzed Silylation and Hydrolytic Oxidation of Organosilanes for the Synthesis of Functional Siloxanes Yang K.-F., Chen X.-H., ^$Lai G.-Q., Jiang J.-X., ^*Xu L.-W.
17:00 00118 Synthesis of Silicon-Containing Epoxy Resin and its Application in IC Packaging Materials ^*Yang M.
17:00 00119 Synthesis and Characterization of an Amidinate-Stabilized Germatrisilacyclobutadiene Ylide Yeong H.-X., Zhang S.-H., Xi H.-W., Guo J.-D., Lim K.H., Nagase S., ^*So C.-W.
17:00 00120 Triorganylsiloxyalkyltetrahydro(iso) and -silaisoquinolines as Novel Candidates for Silyl Prodrugs Zablotskaya A., Segal I., Popelis Yu., Grinberga S., Shestakova I., Nikolayeva V.
17:00 00121 Assessment of Neuroprotection through Activation of the Nrf2-ARE Pathway Using Silicon Derivatives of N-acetyl L-cysteine Zakai U., Reedy M., Williamson T., Amirahmadi S., Johnson D., Johnson J., ^*$West R.
17:00 00122 Synthesis of the First Silenyllithium Li(R'3Si)Si=C(SiR3)1-Ad. Towards the First Silyne Zborovsky L., Dobrovetsky R., Bravo-Zhivotovskii D., Botoshansky M., ^$Apeloig Y.
17:00 00123 Thiol Functionalized PDMS Surface for Improvement of Hydrophilicity Zhang J., Chen Y., ^*Brook M.A.
17:00 00124 Synthesis, Characterization and Reactivity of an Amidinate-Stabilized Silylsilylene Zhang S.-H., Yeong H.-X., ^*$So C.-W.

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Bold text denotes the presenting author.   If present, ^* denotes the corresponding author and ^$ denotes the principal investigator.

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