16th International Symposium On Silicon Chemistry


Tuesday PM

Room MDCL1305-07

Flash Presentations

Chair(s) - Joseph Lambert

13:25 Flash Presentations selected from the Tuesday poster session

13:55 End of Session

Room MDCL1102

Multiple Bonds

Chair(s) - Robert West

A 30-Year Celebration of Stable Double Bonds to Silicon

14:00 00148 Synthesis, Structure and Reactivity of Kinetically Stabilized 1,2-Diaryl-1,2-dihydrodisilenes *Tokitoh N., Agou T., Sugiyama Y., Sasamori T., Takagi N., Nagase S.
14:30 00149 Syntheses of Si2N2 4-Membered Ring Biradicaloids by the Reaction of Disilyne with Azobenzenes Takeuchi K., Ichinohe M., *Sekiguchi A.
14:50 00150 Reactivity of Stable 1,2-Diaryldisilyne $Sasamori T., Han J.S., Guo J.-D., Nagase S., *Tokitoh N.
15:10 00151 Facile Thermal Dissociation of Dibromodisilenes to Bromosilylenes and their Trapping as Lewis Base Adducts Suzuki K., *Matsuo T., Hashizume D., $Tamao K.
15:30 Coffee Break
15:50 00152 A Theoretical Study of Mechanisms of Thermal Cleavage of the E=E Double Bond in Heavy Butadiene Systems (E = C, Si, Ge, Sn and Pb) Sheu J.-H., *$Su M.-D.
16:10 00153 A New Family of p-Conjugated Silicon Compounds Stabilized by the Bulky Rind Groups *Matsuo T., Suzuki K., Li L., Kobayashi M., Hashizume D., Fueno H., Tanaka K., $Tamao K.
16:30 00154 The Variations on a Theme of a Cyclobutadiene Dianion: Silicon and Germanium Versions *Lee V.Ya.
17:00 End of Session

Room MDCL1105

Silicon: The Main Group Element

Chair(s) - Gerald Larson

14:00 00155 Coordination Chemistry of bis(Silyl) Substituted Stannylenes *$Marschner C., Arp H., Hlina J., Baumgartner J., Müller T.
14:30 00156 Solid State 119NMR Spectroscopy of Cationic Tin(II) Complexes Hanson M.A., Avery J.C., Huang Y., *$Baines K.M.
14:50 00157 Synthesis and Structure of New Pyrazolyl Functionalized Potassium Silanides McNerney B., $Krempner C., *Whittlesey B.
15:10 00158 Reactivity of Silicon Grease towards Main Group Organometallic Compounds *$Ruzicka A., Padelkova Z.
15:30 Coffee Break
15:50 00159 H-Ar Ligand Exchange between Silicon and Boron in o-(Hydrosilyl)(diarylboryl)benzenes and Subsequent Intramolecular Cyclization: Formation of Dibenzosilaborins *$Kawachi A., Morisaki H., Yamamoto Y.
16:10 00160 Dipyrrins as Bidentate Ligands in the Coordination Sphere of Silicon *Kämpfe A., $Wagler J., Kroke E.
16:30 00161 Novel Metallosilane Reagents and their Reactions Bravo-Zhivotovskii D., Dobrovetsky R., Zborovsky L., Sheberla D., Molev G., Molev V., Botoshansky M., Apeloig Y., Shimada S.
17:00 End of Session

Room MDCL1309

Silicon Surfaces and Nanostructures

Chair(s) - Mark Fink

14:00 00162 Photochemical Etching and Size-Selected Surface Modification of Silicon Nanocrystals *$Veinot J.G.C.
14:30 00163 Growth and Insulating Properties of Densified SiO2 Ultra Thin Films Grown by VUV Photo-Oxidation Fukano A.F., Oyanagi H.O., Hashimoto H.H., Hata N.H., Takada S.T.
14:50 00164 Mesoporous Silica Encapsulation of Si-NCs: Synthesis of a High Surface Area, Porous, Fluorescent Material Regli S., Kelly J.A., *$Veinot J.G.C.
15:10 Coffee Break
15:50 00165 Disilenes and Digermenes as Molecular Models for the Reactivity of Dimers on Si- and Ge(100)-2x1 Surfaces *$Baines K.M.
16:10 00166 Mimicking the Silicon Surface: Reactivity of Silyl Radicals and Silyl Radical Cations Rijksen B., Van Lagen B., *$Zuilhof H.
16:30 End of Session

Room MDCL1110

Structured Silicones

Chair(s) - William Schulz

14:00 00167 Synthesis of Branched Silanes and Siloxanes Rieger B.
14:30 00168 Nonlinear Light Propagation During Photopolymerization of Methacrylate-Modified Siloxanes Ponte M., Hudson A., Kasala K., Qiu L., Saravanamuttu K.
14:50 00169 Synthesis and Characterization of Asymmetrical Polysiloxanes with a Bulky Alkyl Side Group Vallejo M. J., $Villegas A., Jacobo A., Martinez J.M., Ramírez E., *Cervantes J.
15:10 00170 A Facile, One-Step, Self-Catalysed, Synthesis of High Molecular Weight Hyper-Branched Polydimethylsiloxanes from Commercially Available Reagents *$Holder S.J., Robin M.P.
15:30 Coffee Break
15:50 00171 Geminal Spin-Spin 2J(29Si-O-29Si) Couplings in Silicones and Silicates *$Schraml J., Kurfürst M., Blechta V.
16:10 00172 Low Temperature Curing of T-(phenyl-co-vinyl)siloxane Resin for Plastics Coating *$Nakano T., An K.H.
16:30 00173 Development of New «Tin Free » Polycondensation System Pouget E., $Maliverney C., Ireland T., Schanen S., Blanc D., Saint-Jalmes L., *Vovelle L.
17:00 End of Session

MUSC Marketplace

Posters

Chair(s) - William Leigh

From 17:00 until 19:00

17:00 00174 Remarkably Stable Silicon Analogues of Amide Enolates: Synthesis, Structural Characterization and Reactivity Studies Guliashvili T., Martel A., Alvi M.R., *Ottosson H.
17:00 00175 Solvent Effects on Molecular Interactions and Morphology of Epoxy/Silica Ceramers *$Bakhshandeh E., Jannesari A., Ranjbar Z.
17:00 00176 Mechanistic Insight into the Diastereoselective Synthesis of Silicon-Stereogenic N,O-Difunctionalized Silanes Bauer J.O., *Strohmann C.
17:00 00177 A SET Pathway to Products of the 1,2-Brook Rearrangement Bravo-Zhivotovskii D., Zborovsky L., Molev V., Kaushansky A., Botoshansky M., Tumanskii B., $Apeloig Y.
17:00 00178 Study of Siloles and Optical Properties Related to Coordination with Metal Ions Carroll J.B., *$Braddock-Wilking J.
17:00 00179 Bioinspired Synthesis of Silica Structures Mediated by a Rationally Designed Peptide and a Bioengineered Virus $Chiacchia M., Bassindale A.R., Taylor P.G.
17:00 00180 Convenient Synthesis of Functional Benzylsilanes by Palladium Complex-Catalyzed Three-Component Reactions Cui Y., *Hu Z.
17:00 00181 Novel Metal-Free Polymerization of Silanes: Synthesis of Branched Polyphenylsilanes UsingTris(pentafluorophenyl)borane as Catalyst Deller K., Feigl A., Chiorescu I., Buchner M.R., Karttunen V., Bockholt A., Genest A., Rösch N., Rieger B.
17:00 00182 Syntheses and Reactivity of Cyclic Tetrasiloxanetetraols containing Various Organic Substituents $Unno M., Takeda N., *Endo H.
17:00 00183 Photoresponsive Silicones for Ophthalmic Drug Delivery Fawcett A.S., $Brook M.A.
17:00 00184 Synthesis of Drug Encapsulated Silica Nano-Sized Particles for Controlled Drug Release Fernandes M.D., $Sheardown H.D.
17:00 00185 The Quest for the First Stable Cyclic Di(oligosilyl)silylene Dzambaski A., Flock M., Hassler K.
17:00 00186 Side Chain Polysiloxanes with Conjugated Discotic Structures: New Materials for FET OTFT Sensors? *$Ganicz T., Stanczyk W.A., Makowski T., Tracz A.
17:00 00187 Terphenyl Substituted Silyl Cations - Unexpected Transformations due to Solvent Interaction Gerdes C., $Müller T.
17:00 00188 Bipyridine-Based Hybrid Materials for Applications in Photonics *Graffion J., Nobre S.S., Cattoën X., Ferreira R.A.S., Wong Chi Man M., Carlos L.D.
17:00 00189 Facile Siliconization of Arylamines to Make Pendant Polymers Using Piers-Rubinsztajn Chemistry Gretton M.J., Kamino B.A., *$Bender T.P.
17:00 00190 Mechanistic Studies of the Reactions of Transient Silylene-Ether Complexes with Acids and Bases in Ether/Hexanes Mixtures Hayes R.L.C., Kostina S.S., *$Leigh W.J.
17:00 00191 The Synthesis, Characterisation and Application of Perylene and Perylenetetracarboxylic Dianhydride Triethoxysilane Derivatives *$Holder S.J., Roberts D.R.T., Murphy J.J., Patel M.
17:00 00192 Properties and Pyrolysis of Poly(silacetylene silazane)s *Hu J.
17:00 00193 Properties and Prospects of Nanostructured Silicon Islam M., $Yukiko H.
17:00 00194 Multiple Si=Si Functionalities in the Periphery of Conjugated Aromatic Amines *Jeck J., Bejan I., $Scheschkewitz D.
17:00 00195 Hybrid Carbosilanecyclosiloxane Dendrimers: Synthesis and Properties Investigation Katarzhnova E.Yu., Muzafarov A.M., Ignat'eva G.M.
17:00 00196 From Cyclohexasulfur to Cyclohexasilane: A Quantum Chemical and Raman Spectroscopic Study Kern T., Flock M., Fischer R., $Hassler K.
17:00 00197 Biological Response to Highly Wettable Silicone Surfaces $Brook M.A., Khan M.F., Chen Y., Whinton M.
17:00 00198 Monte Carlo Uncertainty Analysis of a Fugacity-Based Multimedia Mass-Balance Model for Decamethylcyclopentasiloxane (D5) *$Kim J., Powell D.E., Hughes L., Mackay D.
17:00 00199 Air-Stable Diaryldisilenes Emissive at Room Temperature: Synthesis and Application Kobayashi M., *Matsuo T., Hashizume D., Fukunaga T., $Tamao K., Fueno H., Tanaka K., Furukawa S., Tsuji H., Nakamura E.
17:00 00200 Nucleophilic Substitution of Benzyl Groups in Tetraorganosilanes with Alkyllithium Compounds Koller S.G., *Strohmann C.
17:00 00201 Silylative Coupling of Terminal Alkynes with Iodosilanes: New Catalytic Activation of sp-Hybridized Carbon-Hydrogen Bond $Kownacki I., Dudziec B., Kubicki M., *Marciniec B.
17:00 00202 Zwitterionic Alkaline Metal Silanides and Formation of Heterobimetallic Silanides Li H., Hope-Weeks L., *$Krempner C.
17:00 00203 Synthesis and Mechanical Properties of Fluorosilicone Elastomer Based on Poly[(3,3,3-trifluoropropyl)methylcyclotrisiloxane] Liu Y.T., $Zhou C.J., *Feng S.Y.
17:00 00204 Immobilization of T4 Bacteriophages onto Silica Paper Surfaces *Luong N., $Brook M.A. WITHDRAWN
17:00 00205 Influence of Different Ions on Reaction between Silicate and Hydroxoaluminate (Geopolymerisation) in Aqueous Solution Melar J., *Bednarík V., Filák A.
17:00 00206 Synthetic Studies of a Stable 1-Fluoro-2-hydrosilene Mieda E., Sasamori T., Sase S., Goto K., *Tokitoh N.
17:00 00207 Amorphous Silatrane/Lithium Salt Complexes and their Ionic Conductivity $Mizumo T., *Ohshita J.
17:00 00208 A DFT Study on the Structural and Electronic Properties of Symmetrically Substituted C12Si8 and C12Si8X8, (X = H, F and NH2) Heterofullerenes Naderi F., Momeni M.R., Shakib F.A.
17:00 00209 Electroinsulating Silicone Compounds Based on Fines of Organic and Inorganic Silicon Compounds Nanush'yan S.R., Semenkova N.Yu., Polivanov A.N., Storozhenko P.A.
17:00 00210 Novel Synthesis of PEGylated Silica Nanoparticles (SNPs) for Biomedical Applications Natte K., Orts G., Österle W., *$Friedrich J.
17:00 00211 Vapor Pressure of Four Silicone Compounds and Excess Molar Volume of 2, 4, 6, 8-Tetramethylcyclotetrasiloxane + Xylene at 288.15, 298.15 and 308.15 K Dong H., $Wu C., Lai G., *Jiang J.-X., Ni Y.
17:00 00212 Synthesis and Structure of First Isolable Oligo(silyl radical)s Bridged by a Benzene Ring Nozawa T., Nagata M., Ichinohe M., *Sekiguchi A.
17:00 00213 D3 and V3 Diblock Copolymers as Starting Materials for Ceramic Precursors Nyczyk A., Klimek A., Paluszkiewicz C., Szumera M., Grabowski G., Rutkowski P., Hasik M.
17:00 00214 Reactivity of Silane Substituted Stannylenes and Lithium Salts towards Cummulated Multiple Bonds *$Padelkova Z., Ruzicka A.
17:00 00215 Possible Responsibility of Silicone Materials for Degradation of the CO2 Removal System in the International Space Station Baeza M., Sharma H.K., Borrok D., Ren M., Pannell K.H.
17:00 00216 Preparations and Characterizations of Various Cyclopolysilanes Park S.J., Cho H.M., *Lee M.E.
17:00 00217 Organosilicon Compounds for Energy Storage Peña-Hueso A., *$West R.
17:00 00218 Donor-Stabilized Arsasilene with a HSi=AsH Subunit *Praesang C., Stoelzel M., Inoue S., $Driess M.
17:00 00219 Mesoporous Carbon Ceramic SiO2/C Prepared by Sol-Gel Method and Modified with Copper Phthalocyanine and used as an Amperometric Sensor for 4-Aminophenol *Rahim A., Kubota L.T., $Gushikem Y. WITHDRAWN
17:00 00220 Reactive Silicone Elastomers: Synthesis and Applications Rambarran T., *Gonzaga F., $Brook M.A.
17:00 00221 Functionalized Silyl-BINOLs. Building Blocks for Chiral Sila-Macrocycles $Beckmann J., Rivas King N.
17:00 00222 New Silyl(germyl)hetarylbenzimidazoles: Synthesis and Cytotoxic Activity $Ignatovich L., *Romanovs V., Starkova O., Domrachova I., Shestakova I.
17:00 00223 Functional Poly(phenylalkylsilane)s and their Applications in the Synthesis of Silver and Gold Nanoparticles Sahoo U., *$Shankar R.
17:00 00224 An Enzymatic Approach to the Synthesis of Disiloxane-Containing Materials Séguin J.P., Frampton M.B., *$Zelisko P.M.
17:00 00225 Computational Investigations of the Reactivities and Mechanisms of Cycloaddition Reactions of Trimetallaallenes of Group 14 with Alkenes Sheu J.-H., *$Su M.-D.
17:00 00226 Size-Dependent Reactivity in Hydrosilylation of Silicon Nanocrystals Kelly J.A., Shukaliak A.M., Fleischauer M.D., *$Veinot J.G.C.
17:00 00227 Energy Transfer from Silicon Nanoparticles to Organic Dyes Singh M.P., *$Kauzlarich S.M., Louie A.Y.
17:00 00228 Synthesis of Trilithiosilane and its Transmetalation Song J.H., Cho H.M., *Lee M.E.
17:00 00229 Polymer Films containing Liquid Crystalline Molecules as Intelligent Structures in Optical Applications *$Szelag A., Stanczyk W.A.
17:00 00230 Zwitterionic Silanides of Divalent Metal Cations: Synthesis, Structure and Reactivity Thalangamaarachchige V., *Whittlesey B., $Krempner C.
17:00 00231 Selective Dearylhydroxylation of 2-(Alkylthiomethyl)phenylsilane Derivatives Catalyzed by a Palladium Complex $Ueda T., *Takeda N., Unno M.
17:00 00232 Controlling the Photoresponse of Aggregated Silica-Capped Gold Nanoparticles Vanderkooy A., *$Brook M.A.
17:00 00233 Novel Passive Sampling Device for Mercury Monitoring Using Hybrid Sol-Gel Crosslinked Materials *$Vreugdenhil A.J., Stotesbury T.E., Hintelmann H.H., Bliard C.
17:00 00234 Zwitterionic and Anionic Multinuclear Silicon(IV) Complexes with Bridging (R,R)-Tartrato(4-) Ligands: Synthesis aAnd Reactivity in Aqueous Solution Weiss J., Theis B., Lippert W.-P., Bertermann R., Burschka C., *$Tacke R.
17:00 00235 Schiff Base-Bridged Polysilsesquioxane and its Metal Complexes: Synthesis and Magnetic Properties Wu L.
17:00 00236 A Comparison of Hydrogen Bond Strengths Involved in Polysiloxane-Fumed Silica Suspensions Xu Z., $Huang N., Li Z., *Lai G.
17:00 00237 Degradation of Octamethylcyclotetrasiloxane (D4) and Decamethylcyclopentasiloxane (D5) in Aquatic Sediments Xu S., Miller J., Gerhards R.
17:00 00238 A Modeling Assessment on Air-to-Surface Partitioning for Airborne Cyclic Methylsiloxanes Xu S.
17:00 00239 Intermolecular Silicon-Germanium Crossover and Ring Opening in Hexacoordinate Silacyclobutane, Silacyclopentane and Silacyclohexane Complexes Yakubovich S., Kalikhman I., Gostevskii B., *Kost D.
17:00 00240 Diarylprolinol Ether as Aminocatalyst for the Sequential One-Pot Asymmetric Synthesis of Functionalized Cyclohexanes Shen H., $Yang K.-F., Shi Z.-H., Jiang J.-X., Lai G.-Q., *Xu L.-W.
17:00 00241 Thermal Properties and Dielectric Constant of Epoxy-Functionalized Silsesquioxanes *Yoshida K., Hashimoto K., Ochi M.
17:00 00242 Magnetic Nanostructures of Biological Interest containing Silyl-Modified N-(2-Hydroxyethyl)tetrahydroisoquinolines Segal I., Zablotskaya A., Mishnev A., Maiorov M., Zablotsky D., Blums E., Nikolayeva V.
17:00 00243 Investigation on N-Heterocyclic Silyl Cations Zark P., $Müller T.
17:00 00244 Research on the Design, Synthesis and Properties of Silicon-Containing Chiral Polymers Zhang F.-B., Wu X.-J., Ni Y., *Lai G.-Q., Jiang J.-X.
17:00 00245 Superoleophobic Coatings with Ultra-Low Sliding Angles Based on Silicone Nanofilaments Zhang J.P., *Seeger S.
17:00 00246 Preparation of Micro/Nano Organosilicon Microspheres *Zhu Q., Bai R.


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Bold text denotes the presenting author.   If present, * denotes the corresponding author and $ denotes the principal investigator.

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